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Di erent valence states are also a fairly widespread type of unit variability. By analogy with macromolecular complexes (Section II), it may be expected that homopolymerization and copolymerization of metal-containing monomers would prevent or retard redox processes involving participation of metal ions. Experimental data con rm the fact that a polymeric matrix stabilizes complexes of metals in low oxidation states (e.g., Pd ).77 Moreover, the stability of the Cu state during polymerization (including thermal polymerization) of copper acrylate controls the use of this method for the preparation of coordination compounds of Cu .78 The polymeric framework plays a stabilizing role, whereas the metal ions that are localized on the surface layer are oxidized79 to Cu2 . However, polymerization of monomers that contain metal ions in high oxidation states is often accompanied by their reduction: V5 V4 V3 , Fe3 Fe2 , and Mo5 Mo4 (scheme 14). For example, polymerization of Cu2 and Fe3 acrylates may be accompanied by intramolecular chain termination.80 This may be attributed to the relatively low standard reduction potentials of these metal ions (Eo(Cu2 Cu ) 0.15, Eo(Fe3 Fe2 ) 0.77 V).

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3.5 4.5

About the same time that those involved in software engineering were looking for alternatives to the waterfall lifecycle, so too were people involved in HCI looking for alternative ways to support the design of interfaces. In 1989, the Star lifecycle

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SUMMARY The connectedness of systems with clients and partners must be done with careful regard to the threats that may be introduced to the organization. The organization must be completely aware of how the systems are being connected and the scope of the permissions being granted to both parties. Beyond the accidental release of confidential pricing or patent information, the organization may simply expose itself to technology-based threats, such as viruses and worms, through these connections. Other threats may appear based on the type of customers the client works for; malicious attackers or poorly monitored environments may expose the company to collateral damage. These threats can impact the organization materially, and depending on the source and contractual requirements, they may introduce punitive damages to the parties responsible.

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At this point in our discussion, it is instructive to present an example of the evaluation of the PEP for space-time codes partially with the intent of validating the row orthogonality of the symbol error matrix assumed in the slow-fading case. For simplicity, we shall consider the Rayleigh fading case. Consider the four-state QPSK space-time code discussed by Tarokh et al. [9,10] (also in Ref. 37) with Lt = 2 transmit antennas and illustrated here in Fig. 14.5. The labeling ii /kk along each branch of the trellis refers to the pair of input bits (ii ) and the corresponding pair of output symbols (kk ) that result from the transition between the states at the beginning and end of the branch. The output symbol notation k refers to the integer multiple of /2 that characterizes the phase in the complex representation of the complex QPSK symbol [i.e., ej (k /2) ]. The QPSK symbols are the elements of the X and X matrices associated with the trellis. Assuming that the correct path is the all-zeros sequence (zero phase for all symbols), then for the shortest error event path of length N = 2 illustrated by

Figure 2.3 Exports from British Columbia, 1992 2006 (Source: Government of Canada 2007)

Even though this fund had the best 5-year track record, it has not been as attractive in the most recent periods. We can gain some additional insight into performance by creating a chart that graphs the movement over time of the 1-year tracking error versus the rolling 1-year value added. These are the two variables that make up the Information ratio. This kind of a chart is sometimes called a snail trail (see Exhibit 14.8). Including the time period over which the observation occurred adds value over simply plotting the risk and return statistics. For example, here we can see that the rolling value added has been falling and the tracking error increasing over the past few periods. EXHIBIT 14.7

for (i = 0; i < N-1; i++) { // calculate continuously compounded return ret = log(prices[i+1]/prices[i]); returns.push_back(ret); sum = sum + ret; } // calculate mean average return ave = sum/N; for (i = 0; i < returns.size() - lag; i++) { var = 0.0; for (j = 0; j < lag; j++) { var += (returns[lag+i-j-1]- ave)*(returns[lag+i-j-1] - ave); } vols.push_back(100*sqrt(var/((lag-1)*(A)))); } i = 0; // print of MA volatilities for (iter = vols.begin(); iter != vols.end(); iter++) { cout << *iter << endl; i++; } return returns; }

FIGURE 4-3 Glycolytic pathway. Although the structures of the sugars are illustrated in their open-chain form, in solution they exist in their respective ring forms.

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